Also means
dinner jacket
Usage Note
Smoking is an invariable masculine noun in Italian (no plural change: gli smoking). It refers specifically to a formal dinner suit or tuxedo, not to the act of smoking (which is fumare). This is a classic false friend for English speakers: indossare uno smoking means to wear a tuxedo, not to be smoking.
Examples
"Indossava uno smoking elegante alla cerimonia."
Natural Translation
He was wearing an elegant tuxedo at the ceremony.

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